Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| Iker Casillas | 26 | Real Madrid |
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| Sergio Ramos | 21 | Real Madrid |
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| Carlos Marchena | 28 | Valencia |
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| Raúl Albiol | 22 | Valencia |
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| Jose Capdevila | 26 | Real Valladolid |
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| Joaquín | 26 | Valencia |
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| Cesc Fàbregas | 20 | Arsenal |
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| David Albelda | 30 | Valencia |
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| Xavi | 27 | Barcelona |
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| Andrés Iniesta | 23 | Barcelona |
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| Raúl Tamudo | 29 | Espanyol |
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