Starting XI & Clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| Iker Casillas | 27 | Real Madrid |
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| Joan Capdevila | 30 | Villarreal |
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| Sergio Ramos | 22 | Real Madrid |
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| Raúl Albiol | 23 | Valencia |
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| Carles Puyol | 30 | Barcelona |
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| Andrés Iniesta | 24 | Barcelona |
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| Xavi | 28 | Barcelona |
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| Marcos Senna | 32 | Villarreal |
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| Santi Cazorla | 23 | Villarreal |
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| David Villa | 26 | Valencia |
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| Daniel Güiza | 28 | Fenerbahçe |
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