Starting XI with clubs
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Full Time
| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Gordon Banks | 32 | Stoke |
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| 2 | Keith Newton | 28 | Everton |
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| 17 | Jack Charlton | 35 | Leeds |
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| 6 | Bobby Moore | 29 | West Ham |
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| 3 | Terry Cooper | 25 | Leeds |
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| 9 | Bobby Charlton | 32 | Man Utd |
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Out: 65' |
| 19 | Colin Bell | 24 | Man City |
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| 4 | Alan Mullery | 28 | Tottenham |
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| 11 | Martin Peters | 26 | Tottenham |
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| 21 | Allan Clarke | 23 | Leeds |
49'
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| 22 | Jeffrey Astle | 28 | West Bromwich Albion |
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Out: 59' |
| 20 | Peter Osgood | 23 |
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In: 59' | |
| 8 | Alan Ball | 25 | Everton |
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In: 65' |
| Coach | Alf Ramsey | 50 |
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