Starting XI with clubs
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Full Time
| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Gianluigi Buffon | 30 | Juventus |
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| 2 | Christian Panucci | 35 | Roma |
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| 6 | Andrea Barzagli | 27 | Palermo |
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| 23 | Marco Materazzi | 34 | Internazionale |
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Out: 55' |
| 19 | Gianluca Zambrotta | 31 | Barcelona |
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35'
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| 8 | Gennaro Gattuso | 30 | Milan |
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51'
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| 21 | Andrea Pirlo | 29 | Milan |
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| 13 | Massimo Ambrosini | 31 | Milan |
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| 16 | Mauro Camoranesi | 31 | Juventus |
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Out: 75' |
| 9 | Luca Toni | 31 | Bayern |
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26'
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| 11 | Antonio Di Natale | 30 | Udinese |
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Out: 64' |
| 3 | Fabio Grosso | 30 | Lyon |
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In: 55' |
| 7 | Alessandro Del Piero | 33 | Juventus |
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In: 64' |
| 18 | Antonio Cassano | 25 | Sampdoria |
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In: 75' |
| Coach | Roberto Donadoni | 44 |
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