Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 23 | Johnny Herrera | 32 | Universidad de Chile |
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| 4 | Mauricio Isla | 25 | Juventus |
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| 17 | Gary Medel | 26 | Cardiff |
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| 18 | Gonzalo Jara | 28 | Nottingham Forest |
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| 15 | Jean Beausejour | 29 | Wigan |
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Out: 76' |
| 20 | Charles Aránguiz | 24 | Internacional |
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Out: 80' |
| 5 | Francisco Silva | 28 | Osasuna |
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Out: 83' |
| 16 | Felipe Gutiérrez | 23 | Twente |
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21'
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| 8 | Arturo Vidal | 26 | Juventus |
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| 7 | Alexis Sánchez | 25 | Barcelona |
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| 11 | Eduardo Vargas | 24 | Valencia |
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Out: 86' |
| 10 | Jorge Valdivia | 30 | Palmeiras |
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In: 76' |
| 19 | Fabián Orellana | 28 | Celta de Vigo |
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In: 80' |
| 3 | Marcos González | 33 | Flamengo |
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In: 83' |
| 9 | Mauricio Pinilla | 30 | Cagliari |
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In: 86' |