Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Claudio Bravo | 33 | Man City |
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| 4 | Mauricio Isla | 28 | Cagliari |
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| 17 | Gary Medel | 29 | Internazionale |
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| 18 | Gonzalo Jara | 31 | Universidad de Chile |
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| 15 | Jean Beausejour | 32 | Universidad de Chile |
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| 20 | Charles Aránguiz | 27 | Leverkusen |
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11'
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Out: 90' |
| 5 | Francisco Silva | 31 | Cruz Azul |
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Out: 70' |
| 19 | Pablo Hernández | 30 | Celta de Vigo |
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86'
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| 6 | José Pedro Fuenzalida | 32 | Universidad Católica |
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15'
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Out: 55' |
| 11 | Eduardo Vargas | 27 | Tigres |
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| 7 | Alexis Sánchez | 28 | Arsenal |
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| 22 | Nicolás Castillo | 24 | Pumas |
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In: 55' |
| 10 | Jorge Valdivia | 33 | Al-Wahda |
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In: 70' |
| 9 | Esteban Paredes | 36 | Colo-Colo |
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In: 90' |
| Coach | Juan Antonio Pizzi | 48 |
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