Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Claudio Bravo | 34 | Man City |
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| 4 | Mauricio Isla | 29 | Cagliari |
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| 13 | Paulo Díaz | 22 | San Lorenzo |
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| 18 | Gonzalo Jara | 31 | Universidad de Chile |
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| 2 | Eugenio Mena | 28 | Sport |
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| 8 | Arturo Vidal | 30 | Bayern |
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57'
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| 5 | Francisco Silva | 31 | Cruz Azul |
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| 20 | Charles Aránguiz | 28 | Leverkusen |
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Out: 46' |
| 6 | José Pedro Fuenzalida | 32 | Universidad Católica |
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Out: 46' |
| 11 | Eduardo Vargas | 27 | Tigres |
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67'
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Out: 82' |
| 7 | Alexis Sánchez | 28 | Arsenal |
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| 10 | Pablo Hernández | 30 | Celta de Vigo |
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75'
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In: 46' |
| 16 | Martín Rodríguez | 22 | Cruz Azul |
67'
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In: 46' |
| 21 | Marcelo Díaz | 30 | Celta de Vigo |
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In: 82' |
| Coach | Juan Antonio Pizzi | 49 |
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