Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Iker Casillas | 27 | Real Madrid |
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| 15 | Sergio Ramos | 22 | Real Madrid |
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| 5 | Carles Puyol | 30 | Barcelona |
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| 4 | Carlos Marchena | 28 | Valencia |
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| 11 | Joan Capdevila | 30 | Villarreal |
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| 6 | Andrés Iniesta | 24 | Barcelona |
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50'
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| 19 | Marcos Senna | 31 | Villarreal |
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| 8 | Xavi | 28 | Barcelona |
50'
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Out: 69' |
| 21 | David Silva | 22 | Valencia |
82'
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| 7 | David Villa | 26 | Valencia |
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Out: 35' |
| 9 | Fernando Torres | 24 | Liverpool |
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Out: 69' |
| 10 | Cesc Fàbregas | 21 | Arsenal |
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82'
73'
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In: 35' |
| 14 | Xabi Alonso | 26 | Liverpool |
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In: 69' |
| 17 | Daniel Güiza | 27 | Mallorca |
73'
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In: 69' |
| Coach | Luis Aragonés | 69 |
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