Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Claudio Bravo | 33 | Barcelona |
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| 6 | José Pedro Fuenzalida | 31 | Universidad Católica |
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| 17 | Gary Medel | 28 | Internazionale |
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Out: 60' |
| 18 | Gonzalo Jara | 30 | Universidad de Chile |
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| 15 | Jean Beausejour | 32 | Colo-Colo |
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Out: 73' |
| 20 | Charles Aránguiz | 27 | Leverkusen |
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| 21 | Marcelo Díaz | 29 | Celta de Vigo |
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Out: 57' |
| 8 | Arturo Vidal | 29 | Bayern |
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87'
49'
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39'
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| 22 | Edson Puch | 30 | LDU |
87'
16'
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| 11 | Eduardo Vargas | 26 | Hoffenheim |
74'
57'
52'
44'
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| 7 | Alexis Sánchez | 27 | Arsenal |
49'
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52'
44'
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| 5 | Francisco Silva | 30 | Jaguares |
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In: 57' |
| 3 | Enzo Roco | 23 | Espanyol |
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In: 60' |
| 14 | Mark González | 31 | Sport |
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In: 73' |
| Coach | Juan Antonio Pizzi | 48 |
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