Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| Iker Casillas | 27 | Real Madrid |
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| Sergio Ramos | 22 | Real Madrid |
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| Gerard Piqué | 22 | Barcelona |
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| Raúl Albiol | 23 | Valencia |
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| Joan Capdevila | 31 | Villarreal |
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| Xavi | 29 | Barcelona |
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| Xabi Alonso | 27 | Liverpool |
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| Marcos Senna | 32 | Villarreal |
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| Santi Cazorla | 24 | Villarreal |
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| Fernando Torres | 25 | Liverpool |
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| David Villa | 27 | Valencia |
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