Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Iker Casillas | 29 | Real Madrid |
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| 15 | Sergio Ramos | 24 | Real Madrid |
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| 3 | Gerard Piqué | 23 | Barcelona |
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| 5 | Carles Puyol | 32 | Barcelona |
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| 11 | Joan Capdevila | 32 | Villarreal |
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| 8 | Xavi | 30 | Barcelona |
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| 14 | Xabi Alonso | 28 | Real Madrid |
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Out: 73' |
| 16 | Sergio Busquets | 21 | Barcelona |
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| 6 | Andrés Iniesta | 26 | Barcelona |
37'
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| 9 | Fernando Torres | 26 | Liverpool |
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Out: 55' |
| 7 | David Villa | 28 | Valencia |
24'
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37'
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| 10 | Cesc Fàbregas | 23 | Arsenal |
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In: 55' |
| 20 | Javi Martínez | 21 | Athletic Club |
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In: 73' |
| Coach | Vicente del Bosque | 59 |
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