Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 23 | Johnny Herrera | 36 | Universidad de Chile |
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| 4 | Mauricio Isla | 29 | Cagliari |
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| 17 | Gary Medel | 29 | Internazionale |
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Out: 71' |
| 18 | Gonzalo Jara | 31 | Universidad de Chile |
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| 15 | Jean Beausejour | 33 | Universidad de Chile |
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80'
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| 20 | Charles Aránguiz | 28 | Leverkusen |
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Out: 90' |
| 21 | Marcelo Díaz | 30 | Celta de Vigo |
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| 10 | Pablo Hernández | 30 | Celta de Vigo |
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| 11 | Eduardo Vargas | 27 | Tigres |
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Out: 82' |
| 8 | Arturo Vidal | 30 | Bayern |
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6'
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| 7 | Alexis Sánchez | 28 | Arsenal |
6'
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64'
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| 13 | Paulo Díaz | 22 | San Lorenzo |
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In: 71' |
| 16 | Martín Rodríguez | 22 | Cruz Azul |
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In: 82' |
| 5 | Francisco Silva | 31 | Cruz Azul |
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In: 90' |
| Coach | Juan Antonio Pizzi | 49 |
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