Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 12 | Víctor Valdés | 31 | Barcelona |
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| 17 | Álvaro Arbeloa | 30 | Real Madrid |
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| 3 | Gerard Piqué | 26 | Barcelona |
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| 15 | Sergio Ramos | 27 | Real Madrid |
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| 18 | Jordi Alba | 24 | Barcelona |
88'
3'
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| 6 | Andrés Iniesta | 29 | Barcelona |
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| 16 | Sergio Busquets | 24 | Barcelona |
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| 8 | Xavi | 33 | Barcelona |
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| 11 | Pedro | 25 | Barcelona |
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Out: 75' |
| 14 | Roberto Soldado | 28 | Valencia |
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Out: 60' |
| 10 | Cesc Fàbregas | 26 | Barcelona |
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Out: 54' |
| 21 | David Silva | 27 | Man City |
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In: 54' |
| 0 | Fernando Torres | 29 | Chelsea |
62'
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In: 60' |
| 7 | David Villa | 31 | Barcelona |
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In: 75' |