Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Claudio Bravo | 33 | Man City |
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16'
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| 4 | Mauricio Isla | 28 | Cagliari |
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| 3 | Enzo Roco | 24 | Cruz Azul |
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| 18 | Gonzalo Jara | 31 | Universidad de Chile |
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| 2 | Eugenio Mena | 28 | São Paulo |
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| 20 | Charles Aránguiz | 27 | Leverkusen |
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| 21 | Marcelo Díaz | 29 | Celta de Vigo |
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Out: 50' |
| 8 | Arturo Vidal | 29 | Bayern |
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| 14 | Pablo Hernández | 29 | Celta de Vigo |
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| 11 | Eduardo Vargas | 26 | Hoffenheim |
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Out: 74' |
| 7 | Alexis Sánchez | 27 | Arsenal |
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| 17 | Nicolás Castillo | 23 | Universidad Católica |
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In: 50' |
| 19 | Junior Fernandes | 28 | Dinamo Zagreb |
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In: 74' |
| Coach | Juan Antonio Pizzi | 48 |
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