Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| 1 | Claudio Bravo | 34 | Man City |
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| 4 | Mauricio Isla | 29 | Fenerbahçe |
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| 17 | Gary Medel | 30 | Beşiktaş |
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| 18 | Gonzalo Jara | 32 | Universidad de Chile |
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| 2 | Eugenio Mena | 29 | Sport |
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| 8 | Arturo Vidal | 30 | Bayern |
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59'
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| 5 | Francisco Silva | 31 | Cruz Azul |
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51'
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Out: 90' |
| 16 | Pablo Hernández | 30 | Celta de Vigo |
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| 10 | Jorge Valdivia | 33 | Colo-Colo |
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22'
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25'
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Out: 83' |
| 11 | Eduardo Vargas | 27 | Tigres |
22'
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Out: 80' |
| 7 | Alexis Sánchez | 28 | Arsenal |
85'
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| 21 | Martín Rodríguez | 23 | Cruz Azul |
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In: 80' |
| 14 | Felipe Gutiérrez | 26 | Internacional |
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In: 83' |
| 20 | Erick Pulgar | 23 | Bologna |
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In: 90' |
| Coach | Juan Antonio Pizzi | 49 |
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