Starting XI with clubs
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| No | Name | Age | Club | Goal | Assist | Card | Sub. |
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| Quim | 32 | Benfica |
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| José Bosingwa | 26 | Chelsea |
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| Pepe | 25 | Real Madrid |
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| Ricardo Carvalho | 30 | Chelsea |
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| Paulo Ferreira | 29 | Chelsea |
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| Raúl Meireles | 25 | Porto |
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| Nani | 21 | Man Utd |
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| Maniche | 30 | Atlético Madrid |
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| Deco | 31 | Chelsea |
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| Simão | 28 | Atlético Madrid |
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| Hugo Almeida | 24 | Bremen |
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